Research Article | Published: 01 June 2003

Studies on chemical modification of some hardwoods

Manoranjan  Mohanty and Ashwini K. Sharma

Indian Journal of Forestry | Volume: 26 | Issue: 2 | Page No. 107-115 | 2003
DOI: https://doi.org/10.54207/bsmps1000-2003-5583P3 | Cite this article

Abstract

Mainly two chemicals, viz., sodium periodate and chromium (VI) trioxide have been used for chemical modification of hardwoods. Aqueous solution of NalO4 at lower concentrations decreased the dimensional stability (6.97%, 8.37% and 8.93% change in tangential direction for 0.1% concentration and 136 hours water soaking in Bombax ceiba/Red silk cotton tree, Celtis australis/Nettle-tree and Populus deltoides/Eastern poplar, respectively).  Aqueous solution of Cr+6O3 (Chromic acid, 5% for 5 minutes) gave maximum dimensional stability (2.78%, 3.56% and 5.46% change in tangential direction after 136 hours water soaking in Bombax ceiba, Celtis australis and Populus deltoides respectively) followed by combined treatment (1.0% NalO4 for 20 hours followed by 5.0% chromic acid for 5 minutes). Extractive leaching was reduced with the three treatments and was observed minimum in the combined treatment (0.45%, 0.24% and 0.18% after 136 hours water soaking for Bombax ceiba, Celtis australis and Populus deltoides, respectively). Water absorptivity decreased with chromic acid application and was observed minimum in the combined treatment (86.49%, 82.24% and 99.80% after 136 hours water soaking for Bombax ceiba, Celtis australis and Populus deltoides, respectively).

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References

1. Abdurrohim, S. and Martawijaya, A. (1987). Dip diffusion treatment of ten wood species from Irian Jaya. J. Penelitian – Hasil – Hutan, 4(3): 65 – 70.

Google Scholar

2. Anon. (1970). Indian Forest Utilisation. Vol.I. Delhi: Manager of Publications. FRI and Colleges. p. 139.

3. Black, J.M. and Mraz, E.A. (1974). Inorganic surface treatments for USDA. For. Serv. Res. Pap. FPL 232, For. Prod. Lab., Madison, Wis. 40 pp.

4. Chen, G.C. and Rowell, R.M. (1989). Fungal and termite resistance of wood reacted with HIO4 acid or NalO4. Wood and Fibre Sc., 21(2):143-148.

Google Scholar

5. Collett, O. (1987). The effect of Cu, As and Cr compound on the activity. CSIRO, Div. Chem. Wood Techno. Higwett, Victoria, 3190, Australia.

6. Feist, W.C. and Williams, R.S. (1991). Weathering durability of chromium treated Southern pine. Forest Product J., 41(1): 8-14.

Google Scholar

7. Guthrie, R.D. (1961). The “dialdehydes” from the periodate oxidation of carbohydrates. Advances in carbohydrate chemistry, 16: 105-158.  https://doi.org/10.1016/S0096-5332(08)60261-1

Google Scholar

8. Kumar, S. and Dev, Indra (1993). Wood preservation in India. Dehra-Dun: ICFRE. p. (V).

9. Kumar, S. and Jain, V.K. (1976). The effect of wood preservatives on physical properties of wood. Holzforschung und Holzverwertung, 28(2): 37-40.

Google Scholar

10. Pizzi, A. (1979). Wood water proofing and lignin-cross-linking by means of CrO3/guaiacyl units complexes. Holzforschung und Holzverwertung, 31(6): 126-130.

Google Scholar

11. Randle, B.J. (1969). World timbers. Vol. II. North and South America. London: Ernest Benn Limited. p. 40.

12. Sharma, R.S. (1993). Acetylation and chromium fixation on some hardwood species. Solan : UHF. 380 pp.  M.Sc. – thesis (1993) – Deptt. of For. Prod., UHF, Solan.

Google Scholar

13. Stamm, A.J. (1964). Wood and Cellulose Science. New York: The Ronalds Press Company.

Google Scholar

14. Williams, R.S. and Feist, W.C. (1985). Wood modified inorganic salts: Mechanism and Properties. I. Weathering rate. Wood and Fibre Science, 17(2): 184-198.

Google Scholar

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How to cite

Mohanty, M. and Sharma, A.K., 2003. Studies on chemical modification of some hardwoods. Indian Journal of Forestry, 26(2), pp.107-115. https://doi.org/10.54207/bsmps1000-2003-5583P3

Publication History

Manuscript Published on 01 June 2003

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